Reflections on the use of the mccabe and thiele method. Jul 25, 2007 the feed is a two phase mixture with a feed quality is equal to 0. Perform mccabe thiele method on any vapourliquid data. Where the concentration of the nonkeys is small, say less than. This video is for the purpose of final year project study. Preparation of mccabe thiele plots for each of the experimental trials c develop a model that incorporates the packing mass transfer properties such that the. Scilab is an open source software for numerical computation with a syntax similar to mathworks matlab. Yet some consider graphical techniques tools of the past, and as a result, the distillation column has become a black box and.
Matlab i about the tutorial matlab is a programming language developed by mathworks. Simulation of multistage countercurrent liquidliquid. The yaxis shows the mole fraction of ethanol in the apvor phase, the xaxis shows the mole fraction in liquid phase. The following matlab project contains the source code and matlab examples used for mccabe thiele method gui for binary column distillation. Example 2 devise an enthalpyconcentration diagram for the heptaneethyl benzene system at 760 mm v solution to recitation 1 pdf is posted. Stripping method %put file into matlab to run program. The mccabe thiele diagram used for calculating the number of theoretical steps. The transfer of the components from the feed to the solvent is controlled by the solubility behavior. Jul 12, 2005 binary distillation with the mccabe thiele method binary fractional distillation is a means of separating two liquid components via a distillation column which contains a number of trays, or stages. This simplification can often be made when the amount of the nonkey components is small, or where the components form nearideal mixtures. Visualizing the mccabethiele diagram m ore than 80 years ago, mccabe and thiele developed a creative graphical solution technique based on lewiss assumption of constant molal over. Additionally, it determines the total number of eq stages required and shows the stepdown process.
Mccabethiele graphing for an ideal mixture matlab central. Mccabethiele method of distillation design the mccabe thiele method of distillation design is a graphical method of design that dates back to the early 20 th century. Number of each theoretical tray shows the number of each theoretical tray in the mccabe thiele diagram. Visualizing the mccabethiele diagram m ore than 80 years ago, mccabe and thiele developed a creative graphical solution technique based on lewiss assumption of constant molal over fl ow cmo for the rational design of distillation columns 1. We may also elect to select the mccabe thiele panel. Mccabe theile method for determining theoretical stages in a distilation column purpose of calculation to determine the number of equilibrium stages in a binary distilation column. Mccabethiele method for methanolwater separation wolfram. A mccabe thiele diagram can be obtained by clicking on the mccabe thiele icon on the button bar.
Ternary or triangular diagrams and distillation lines. Next, as shown in figure 1, draw the purple operating line for the stripping section of the. Chemsep starts automatically with a new problem where you are asked to enter a descriptive title for the simulation. Binary distillation column modeling distillation columns. Uses the mccabethiele graphical method to determine the number of equilibrium stages in a distillation column. Use the mccabe and thiele method to determine the number of plates. For instance, a user should have some idea of the column behavior before attempting to use aspen.
Plotting mccabethiele diagrams in microsoft excel for non. My first attempt at making a mccabe thiele program. Simulation on mccabe thiele method with matlab simulator. These lines are derived by writing global and partial material balances around different sections of the column. Mccabethiele method for an ideal binary mixture file. Sep 03, 2018 determination of number of plates by the mccabethiele method example ponchon savarit method fro distillation by padmesht. The separation of a binary waterethanol solution via a. The mccabe thiele method is a graphical procedure to solve alternately the equilibrium relation and the material. With the mccabe thiele method, the total number of necessary plates, as well as the feed plate location can bidd if i lbbe estimated, and some information can also be. Binary distillation using mccabe thiele diagram calculates total number of stages, feed point required to separate a binary mixture with given relative volatility, reflux ratio, feed, bottom, distillate mol.
Vle data of binary mixtures is often presented as a plot, as shown in the figure below. The mccabe thiele method is a graphical procedure to solve alternately the. Keywords distillation mccabethiele computational resources undergraduate. An example of the mccabe thiele diagram for absorption is illustrated in figure 8. Discusses ethanol distillation or ethanol water separation along with mccabe thiele diagram and murphee efficiency.
The aim of this article is to show how scilab can be used to plot the mccabe thiele diagram and simulate the distillation of a binary mixture. Below only the method applying the mccabe thiele diagram is discussed. This excel spreadsheet for mccabethiele method is awesome. The mccabethiele method for the conceptual design of binary distillation columns. The following example is particularly useful in order to assess the applicability of the mccabe and thiele method, especially when compared with other analytical methods, such as fenske 10 and kirkbridge 11 methods. The mccabethiele diagram enabled decades of effective design and operational analysis of. For a good introduction into the intricacies of microsoft excel 2007 which is the version used in this paper see excel 2007, the missing manual9. Simple multicomponent distillation harry kooijman and ross taylor. As can be seen now, the typical mccabe thiele diagram in figure 1 uses a qline representing a partially vaporized feed. Pdf mccabethiele method revisitedsolving binary distillation. The very shape of the hx diagram provides a clue as to the importance of the energy balances. Nov 29, 2017 this video is for the purpose of final year project study. Binary distillation using mccabe thiele diagram calculates total number of stages, feed point required to separate a binary mixture with given relative volatility, reflux ratio, feed, bottom, distillate mol fraction. Chemical and phase equilibrium calculates the equilibrium composition when both liquid and vapor are present for a threecomponent system.
Review and extension of the mccabethiele method covering multiple feeds, products and heat transfer stages. You can manipulate some of the data and see the immediate graphical changes, which kinda puts the method into perspective a bit more clearly. Jun 24, 20 this function creates mccabe thiele diagrams from various user inputs. This demonstration presents the mccabe and thiele graphical method, which is applicable to binary mixtures. It can be run both under interactive sessions and as a batch job. Extractors using mixed integer nonlinear programming techniques. Experienced process engineers often use mccabe thiele diagrams to understand or help debug simulation results 3.
The mccabethiele graphical solution method for binary distillation is used to determine the number of equilibrium stages needed to achieve a specified separation in a distillation column. Ethanol distillation mccabethiele diagram and murphee. Some example qline slopes are presented in figure 2. Pdf at undergraduate level, the separation of binary mixtures is studied using, mainly. Mccabethiele graphical method example part 1 youtube. I think this spreadsheet is stunningly helpful for understanding the mccabe thiele method for the analysis of binary distillation. Txy and xy diagrams, comparison of experimental data and raouls law for methanol and water. It also displays some key distillation parameters such as the reflux and boilup ratios and the feed conditions. Working on the hx diagram is more general than a mccabe thiele construction, because it takes direct account of the thermal effects and does not require an assumption of equimolal overflow. Aspen tutorial chemical engineering and materials science. In this tutorial, we extend the equations from the mccabe thiele method and develop a graphical procedure for three component or ternary mixtures. How do you make the mccabe thiele graphical construction for such a cascade.
We can move the qpoint point of intersection of these lines on the mccabe thiele diagram. The distillate, feed and bottom mole fractions are 0. Practica in process engineering ii extraction introduction extraction is a process in which one or more components are separated selectively from a liquid or solid mixture, the feed phase 1, by means of a liquid immiscible solvent phase 2. Use of process simulation and mccabethiele modeling in. Mccabethiele method revisitedsolving binary distillation problems with nonconventional specifications article pdf available in journal of chemical engineering of japan 419. This function creates mccabe thiele diagrams from various user inputs. It is used as an introductory method to teach the design of distillation and is still in use today by engineers who design distillation columns. Verification of mccabethiele method and determination of. Its one of the blackboxes which appeared in process and performs some physical as opposed to chemical change. Then, we draw the mccabe and thiele diagram see figure. Mar 06, 2014 uses the mccabe thiele graphical method to determine the number of equilibrium stages in a distillation column.
With the mccabethiele method, the total number of necessary plates, as well as the feed plate location can bidd if i lbbe estimated, and some information can also be determined about the enthalpic condition of the feed andrefluxratio. Mccabethiele method revisited solving binary distillation problems with. The mccabe thiele graphical solution method for binary distillation is used to determine the number of equilibrium stages needed to achieve a specified separation in a distillation column. Solving problems use mccabe thiele model to determine the number of equilibrium stages required, given reflux ratio, top and bottom product.
This tutorial gives you aggressively a gentle introduction of matlab programming language. This paper presents a method to automate the process of fitting binary equilibrium data to a smooth curve using a cubic bspline algorithm implemented via visual basic for applications vba in microsoft excel and then drawing the mccabe thiele diagram in microsoft excel. Mccabethiele method for an ideal binary mixture matlab central. This is a classic chemical engineering diagram and shows the number of theoretical stages, the position and slope of the qline, and the relative volatility curve, and the purity of the top and bottom products.
The program computes the number of equilibrium stages for a binary ideal mixture with relative volatility equal to 2. Verification of mccabe thiele method and determination of basic parameters of distillation by using software packages matlab and chemcad for separating of mixture nheptanenoctane. The feed is a two phase mixture with a feed quality is equal to 0. A unit operation is one step in a process to convert a raw material into some useful chemical product. For a good overview of the mccabe thiele method as applied to binary distillation problems, see geankoplis8 pages 706724. Distillationabsorption column design che 4253 design i binary systems. The aim of this article is to show how scilab can be used to plot the mccabe thiele diagram and.
Tkp4105tkp4110 oldershow perforated plate distillation. The number of stages can then be calculated using a mccabe thiele diagram, or the other methods developed for binary systems. A mccabe thiele diagram for the absorption operation from separation process engineering by wankat, 2007. First, the rectifying and stripping operating lines are plotted using a reflux ratio equal to 1. Distillationabsorption column design che 4253 design i 1800 or earlier now. This information could come from an approximate method, such as the mccabe thiele approach, general modeling of the txy behavior, or residue curve maps. Optionally, if you have murphrees efficiency values, a second graph, based on this parameter will appear as well. Learncheme features faculty prepared engineering education resources for students and instructors produced by the department of chemical and biological engineering at the university of colorado boulder and funded by the national science foundation, shell, and the engineering excellence fund. Thiele method because of the advantage to present the results in graphical form. It is about the simulation of mccabe thiele method by using matlab code.
Aspen cannot tell you how many stages to use for a given separation. Simulation of multistage countercurrent liquidliquid extraction annasaheb warade, ravindra gaikwad, rajiv sapkal, and vilas sapkal 82 modified mccabe thiele method the separation achieved for a given number of ideal stages in a counter flow cascade can be determined by using a triangular diagram and special graphical techniques but a. We draw the mccabe and thiele diagram and get the number of theoretical plates equal to 9. The following matlab project contains the source code and matlab examples used for mccabe thiele method for an ideal binary mixture. Stepping off stages course description learncheme features faculty prepared engineering education resources for students and instructors produced by the department of chemical and biological engineering at the university of colorado boulder and funded by the national science foundation, shell, and the engineering excellence fund. Binary distillation with mccabethiele method excel.
A diagram of the enriching operating line can be seen in figure 1. The mccabethiele method of distillation design is a graphical method of design that dates back to the early 20 th century. It started out as a matrix programming language where linear algebra programming was simple. Constant pressure vle data is obtained from boiling point diagrams. Next, as shown in figure 1, draw the purple operating line for the stripping section of the distillation column i. Mccabe thiele method gui for binary column distillation in matlab. Nov 19, 2009 mccabe theile method for determining theoretical stages in a distilation column purpose of calculation to determine the number of equilibrium stages in a binary distilation column.
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